Over the years, celebrity couples have worn everything from elegant ensembles to daring outfits for their first red-carpet moments together.

The can't-miss red carpet looks on your favorite stars from the week's biggest events including Angelina Jolie's effortlessly chic red carpet moment in London to starry New York Fashion Week gatherings.

R.T. The red carpet (and this list) had plenty of roomy, heavy-looking all-black ensembles, but the singer who’s come to be known for barely-there skirts and hard-to-miss innuendos cut the other direction with this soft blue JW Anderson.